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Molecular mechanisms behind free radical scavengers function against oxidative stress

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Then, the INT1-Se undergoes two successive [2,3]-sigmatropic rearrangements 44,45,46,47,48,49 to generate the para -amination intermediate ( INT3-Se ), which may readily react with HBr and then rearomatize to the desired product 2a (for details see Supplementary Figs 411)

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Therefore, the model provides a platform from which the impact of varying degrees of quinone concentration and exposure times on GSH homeostasis may be computationally examined